New oxyfluorotellurates(IV): MTeO3F (M = FeIII, GaIII and CrIII).

نویسندگان

  • Jean Paul Laval
  • Nefla Jennene Boukharrata
  • Philippe Thomas
چکیده

The crystal structures of the new isomorphous compounds iron(III) oxyfluorotellurate(IV), FeTeO(3)F, gallium(III) oxyfluorotellurate(IV), GaTeO(3)F, and chromium(III) oxyfluorotellurate(IV), CrTeO(3)F, consist of zigzag chains of MO(4)F(2) distorted octahedra alternately sharing O-O and F-F edges and connected via TeO(3) trigonal pyramids. A full O/F anionic ordering is observed and the electronic lone pair of the Te(IV) cation is stereochemically active.

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عنوان ژورنال:
  • Acta crystallographica. Section C, Crystal structure communications

دوره 64 Pt 2  شماره 

صفحات  -

تاریخ انتشار 2008